Si trova su / Altri legami
© 2021 American Chemical Society.A polycrystalline sample of Pb2NiOsO6 was synthesized under high–pressure (6 GPa) and high–temperature (1575 K) conditions. Pb2NiOsO6 crystallizes in a monoclinic double perovskite structure with a centrosymmetric space group P21/n at room temperature. Pb2NiOsO6 is metallic down to 2 K and shows a single antiferromagnetic (AFM) transition at TN = 58 K. Pb2NiOsO6 is a new example of a metallic and AFM oxide with three–dimensional connectivity. Neutron powder diffraction and first–principles calculation studies indicate that both Ni and Os moments are ordered below TN and the AFM magnetic order breaks inversion symmetry. This loss of inversion symmetry driven by AFM order is unusual in metallic systems, and the 3d–5d double–perovskite oxides represent a new class of noncentrosymmetric AFM metallic oxides.
